A peer-reviewed journal published by K. N. Toosi University of Technology

Evaluating the dosimetry response to gamma-rays in HDPE/Bi2O3 and PC/Bi2O3 nanocomposites

Document Type : Research Article

Authors

1 Radiation Application Research School, Nuclear Science and Technology Research Institute, P.O. Box 31485-498, Karaj, Iran

2 School of Medical Imaging, Faculty of Health Sciences, Universiti Sultan Zainal Abidin (UniSZA), Terengganu, Malaysia

3 Department of Medical Radiation Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran

Abstract
The recent emphasis on nanocomposites composed of polymers and metal oxides is largely due to their significant promise as effective radiation sensors, detectors, and dosimeters for gamma rays, X-rays, and charged particles. The sensitivity of a system may be affected by various factors, including the volume of the sensitive material, the concentration of heavy metal oxide nanoparticles, the bias voltage applied, and the degree of crystallinity within the polymer matrix. Studies have shown that a pronounced degree of crystallinity in polymers can restrict the homogeneous spread of nanoparticles. This research utilized two distinct polymer matrices, namely HDPE and PC, to create a nanocomposite that incorporated bismuth oxide nanoparticles at concentrations reaching 60 wt%. FESEM images revealed that PC exhibited better dispersion up to 60 wt%, while HDPE showed agglomeration at 40 wt%. Under a defined dose rate of 42.67 mGy.min-1, and with a fixed amount of Bi2O3 nano-fillers, the dosimetry response (measured as a change in electrical current) of PC was twice as pronounced compared to HDPE. Therefore, PC, as an amorphous polymer containing 50 wt% Bi2O3, may be considered a suitable candidate for dosimetry applications.

Highlights

  • Polymer/bismuth oxide nanocomposites were considered as gamma-ray dosimeters.
  • Two types of polymers were investigated crystalline HDPE, and amorphous PC.
  • The change in electrical current was considered as the dosimetry response.
  • PC exhibited better dispersion up to 60 wt%, while HDPE showed agglomeration at 40 wt%.
  • The amorphous PC at 40 wt% exhibited a higher response rather than HDPE.

Keywords


Chen, J., Huang, X., Jiang, P., et al. (2009). Protection of SEBS/PS blends against gamma radiation by aromatic compounds. Journal of Applied Polymer Science, 112(2):1076–1081.
Gurkalenko, Y. A., Eliseev, D., Zhmurin, P., et al. (2017). The plastic scintillator activated with fluorinated 3-hydroxyflavone. Functional Materials.
Hosseini, M. A., Malekie, S., and Kazemi, F. (2022). Experimental evaluation of gamma radiation shielding characteristics of polyvinyl alcohol/tungsten oxide composite: A comparison study of micro and nano sizes of the fillers. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, 1026:166214.
Intaniwet, A., Mills, C., Shkunov, M., et al. (2012). Heavy metallic oxide nanoparticles for enhanced sensitivity in semiconducting polymer x-ray detectors. Nanotechnology, 23(23):235502.
Kaur, J., Lee, J. H., and Shofner, M. L. (2011). Influence of polymer matrix crystallinity on nanocomposite morphology and properties. Polymer, 52(19):4337–4344.
Kim, J., Seo, D., Lee, B. C., et al. (2014). Nano-W dispersed gamma radiation shielding materials. Advanced Engineering Materials, 16(9):1083–1089.
Kyatsandra, S. and Wilkins, R. (2014). Total ionizing dose X- ray radiation effects on MWCNT/PMMA thin film composites. IEEE Transactions on Nanotechnology, 14(1):152–158.
Malekie, S. and Ziaie, F. (2015). Study on a novel dosimeter based on polyethylene–carbon nanotube composite. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, 791:1–5.
Malekie, S., Ziaie, F., and Esmaeli, A. (2016a). Study on dosimetry characteristics of polymer–CNT nanocomposites: Effect of polymer matrix. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, 816:101–105.
Malekie, S., Ziaie, F., Feizi, S., et al. (2016b). Dosimetry characteristics of HDPE–SWCNT nanocomposite for real time application. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, 833:127–133.
Mark, J. E. et al. (2007). Physical properties of polymers handbook, volume 1076. Springer.
Mehrara, R., Malekie, S., Saleh Kotahi, S. M., et al. (2021). Introducing a novel low energy gamma ray shield utilizing Polycarbonate Bismuth Oxide composite. Scientific Reports, 11(1):10614.
Mosayebi, A., Malekie, S., Rahimi, A., et al. (2019). Experimental study on polystyrene-MWCNT nanocomposite as a radiation dosimeter. Radiation Physics and Chemistry, 164:108362.
Mosayebi, A., Malekie, S., and Ziaie, F. (2017). A feasibility study of polystyrene/CNT nano composite as a dosimeter for diagnostic and therapeutic purposes. Journal of Instrumentation, 12(05):P05012.
Safdari, S. M., Malekie, S., Kashian, S., et al. (2022). Introducing a novel beta-ray sensor based on polycarbonate/bismuth oxide nanocomposite. Scientific Reports, 12(1):2496.
Stix, W., Bottenbruch, L., and Neuray, D. (1985). Poly-carbonates having terminal groups which contain conjugated double bonds. US Patent 4,518,747.
Veiskarami, A., Sardari, D., Malekie, S., et al. (2022). Evaluation of dosimetric characteristics of a ternary nanocomposite based on High Density Polyethylene/Bismuth Oxide/Graphene Oxide for gamma-rays. Scientific Reports, 12(1):18798.
Yadav, R., Naebe, M., Wang, X., et al. (2017). Structural and thermal stability of polycarbonate decorated fumed silica nanocomposite via thermomechanical analysis and in-situ temperature assisted SAXS. Scientific Reports, 7(1):7706.
Volume 5, Issue 4
Autumn 2024
Pages 15-19

  • Receive Date 14 July 2024
  • Revise Date 03 August 2024
  • Accept Date 20 August 2024